Question

Q In NAcL type str of A+ &B- ,2A ATOMS ARE REMOVED FROM EDGES &2B ATOMS ARE REMOVED FROM CORNER. FORMULA=?  ANS =A14B15 . HOW?

Joshi sir comment

In NaCl like structure B covers all the corners and face centre and A covers all the edge centres and body centre

Net contribution of B = 8*1/8 + 6*1/2 = 4

Net contribution of A = 12*1/4 + 1*1 = 4

now 2 A ATOMS ARE REMOVED FROM EDGES so remaining contribution = 10*1/4 + 1*1 = 7/2

and 2 B ATOMS ARE REMOVED FROM CORNE so remainnig contribution = 6*1/8 + 6*1/2 = 15/4

so formula will be A7/2B15/4  or A14B15

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