Question

Q IN THAT Fe QUES ANSWER GIVEN IS -VE 0.405 BUT ACC. TO THIS METHOD ANSWER DO NOT MATCH

Q I STILL DIDNOT  UNDERSTAND  CO & CO2 RELATION

Joshi sir comment

 

Fe                ----->  Fe++  + 2e-         

so E for the new reaction = [1F(0.77) + 3F(0.04)]/2F = 0.89/2 = 0.445

so it will be -0.445 for the reverse, you are asking for reduction and i submitted the answer for oxidation so the duality created.

 

according to the given reaction we get 2L monooxide by 1L dioxide,

initially litres of CO2  = x so it will form 2x litres of CO

and 1-x litres CO are present from the start so total litres of CO = 2x+1-x = 1+x

 

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