Question

in the crystal str of Fe3O4 Fe2+& Fe3+ occupy resp.

50% octatrahedral  &12.5% tetrahedral viods

Joshi sir comment

let atom of O = 1

so 50% Fe++ in octahedral void  = 1*1/2 = 1/2

and 12.5 % Fe+++ in tetrahedral voids = 2*1/8 = 1/4

so total Fe = 1/2 + 1/4 = 3/4

so name of the compound = Fe3/4O  = Fe3O4

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SARIKA SHARMA 12 year ago is this solution helpfull: 2 0

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