Question

an element crystallises in fcc lattice having 400pm. calculate the maxm diameter which can be placed in a interstitial sites without disturbing the str

1) 400pm

2) 117.1 pm

3) 224.2 pm

4) 336.2 pm

Joshi sir comment

according to the given conditions

along the face of a side 4x = 400√2             or  x = 100√2                 here x is radius of the atom forming lattice

and along an edge 2x+2y = 400                      here y is interstitial radius

so y = 200-x = 200-100√2  = 100 (2-1.414) = 100(0.586) = 58.6 pm

so diameter = 117.2

 

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