216 - Chemistry Questions Answers

  what will be the value of molar conductance for 0.001M aqueoussolution for NH3 ? giveen  k =1.6*10-5  and  equivalent conductance=0.0238

 

Asked By: SHUBHAM VED
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Joshi sir comment

NH+ H+(aq) = NH4

0.001                   0                                 at start

0.001(1-α)          0.001α                       at eq.

now k = 0.001α / 0.001(1-α)

solve this equation for α and getconcentration of NH4+

then use the formula molar conductance = eq. conductance / concentration of NH4+

What is basicity of oxalic acid ?

Asked By: ASHISH RANA
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Joshi sir comment

oxalic acid is COOH-COOH so basicity will be 2

starting from benzene

1. 1,2,4 tribromo benzene

2. ortho crisol

3. ortho hydroxy toluene

4. ortho carboxyl toluene

5. m-bromo phenol

Asked By: LOKHESH
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Joshi sir comment

1)  First prepare aniline from benzene via nitro track, it is ortho para director so by bromination 2,4 dibromo aniline will be formed then change NH2 to Br via diazonium track.

2)  First prepare toluene from benzene, then place NHin ortho position and change it into OH via diazonium track.

3)  same as 2.

4)  First prepare toluene from benzene, then place Br in ortho position and change it into COOH via grignard track.

5)  First prepare nitro benzene, it is meta director so form m- bromo nitro benzene, then change nitro to amino and amino to OH via diazonium track. 

which  has smaallest bond length 1.[V(CO)6]- 2.[Mn(CO)6]+ 3.[Cr(CO)6] 3. Fe(CO)5

Asked By: SAHILKUMAR
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Joshi sir comment

2.[Mn(CO)6]+

[V(CO)6]- will be longest

[fe{phen}3]+2 is it dia magnetic

 

Asked By: SAHILKUMAR
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Joshi sir comment

since phen is a strong-field, chelating nitrogen heterocycle so it will force Fe (ii) into a low-spin  t2g6  eg0 electronic configuration with no unpaired electrons so it is diamagnetic

The nitrogen oxide(s) that contain(s) N-N bond(s) is (are) -
(A) N2O (B) N2O3
(C) N2O4 (D) N2O5

Asked By: KAMAL
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Joshi sir comment

(A) N2O      (B) N2O3       (C) N2O4   
These 3 contains N-N bond but in    (D) N2O5    There is 1 oxygen atom between 2 NO2 so this does not contain N-N bond

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