216 - Chemistry Questions Answers

Which among the following is the strongest oxidizing agent and why??    IO4-  BrO4-  ClO4-       

 

Asked By: AAYUSH TANEJA
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Joshi sir comment

 Inertness of BrO4- at room temperature stands in sharp contrast to its high thermodynamic oxidizing power, which is greater than that of any other oxohalogen ion that persists in aqueous solution. The oxidation potential is
BrO4-+ 2H+ + 2e- -------> BrO3- + H2O                              E =  +1.853 V

(1.201 V for ClO4- and 1.653 V for IO4-)

HOW TO COMPARE FOR HEAT OF COMBUSTION ? WHAT MOST BE STRATERGY TO DECIDE WHICH COMPOUD HAVE MORE EAT OF COMBUTION

Asked By: SIDDHANT
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Joshi sir comment

For this it is necessary to remember all the bond energies

A sample of fuming HNO3 is labelled as 110% . assume that the labelling of fuming is similar the labelling of oleum . What is the % of free N2O5 in the sample??

plz annex explanatn also ans is 60%

Asked By: SARIKA
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Joshi sir comment

x % HNO--------------------- 100 + (18/108)*x % of fuming HNO3

so 18x/108 = 10 

or x = 60 %

 

If ionic product of water is Kw = 10-6 at 4°C, then a solution with pH = 7.5 at 4°C will

(i) turns blue litmus red 

(ii) turns red litmus blue

(ii) Be neutral to litmus

Asked By: SWATI KAPOOR
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Joshi sir comment

question is not appropriate because for given Kw , [H+] will be 10-3 and max. pH will be 6 and the question is asking about a solution of pH 7.5 which is out of limit 

but if it is considered as a correct question then answer will be (ii)

N2 + O2 = 2NO . Equilibrium constant Kc = 2 . Degree of dissociation is

(i)  1/1-√2   (ii) 1/1+√2    (iii) 2/1-√2

Asked By: SWATI KAPOOR
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Joshi sir comment

 N2   +    O2   =    2NO 

  1                       1                       0

  1-x                    1-x                  2x

so by formula Kc = (2x)2 / (1-x)(1-x)

now solve for x

In the equilibrium SO2Cl2 = SO2 + Cl2 at 2000K and 10 atm pressure , % Cl2 = % SO2 = 40 (by volume) . Then what is the value of Kp?

Asked By: SWATI KAPOOR
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Joshi sir comment

SO2Cl2 = SO2 + Cl2

100               0           0

20                  40       40

2 atm             4 atm   4 atm

now calculate Kp 

0.2 mole of N2 and 0.6 mole of H2 react to give NH3 and 40 % of reactant mixture is decreased , according to the equation,

N2 (g) + 3H2 (g) =  2NH3 (g) at constant temperature and pressure. Then the ratio of the final volume to the initial volume of gases is

 

Asked By: SWATI KAPOOR
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Joshi sir comment

N2 (g) + 3H2 (g) =  2NH3 (g)

0.2          0.6                0

0.2-x       0.6-3x         2x

according to the given condition 4x = 0.8*40/100 = 0.32

so x = 0.08

now solve

1 mole of A , 1.5 mole of B and 2 moles of C are taken in a vessel volume one litre. At equilibrium concentration of C is 0.5 mole/L. Equilibrium constant for the reaction
A (g) + B (g) = C (g)

Asked By: SWATI KAPOOR
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Joshi sir comment

A (g) + B (g) = C (g)

  1         1.5        2

1-x      1.5-x     2+x

according to the given condition 2+x = 0.5 so x = -1.5

now calculate Kc

The Ksp for a sparingly soluble Ag2CrO4 is 4 x 10-12. The molar solubility of the salt is

Asked By: SWATI KAPOOR
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Joshi sir comment

Ag2CrO-------------> 2Ag + CrO4

s                                            0                  0

                                              2s                 s

so Ksp = (2s)2 s = 4s3

now solve   

A 0.1N solution of sodium bicarbonate has a pH value of

Asked By: SWATI KAPOOR
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Joshi sir comment

Please submit complete question, Ka should be given with percentage of ionisation

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