216 - Chemistry Questions Answers

WHAT OSMOTIC PRESSURE WOULD BE OF 1.25m SUCROSE SOLUTION AT 25C ?DENSITY OF SOLUTION IS 1.34g/mL?

Asked By: SHWETA BHARDWAJ
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Joshi sir comment

formula is πV = nRT or π = MRT,   M is molarity

strength of solution is 1.25m

so 1000 gm water ..............................................1.25 mole sucrose

so 1000 gm water .............................................1.25*342=427.5gm sucrose

so 1427.5 gm solution ....................................1.25 mole sucrose

so 1427.5/1.34=1065.30 ml = 1.0653 L solution ...........................1.25 mole sucrose

so M = 1.25/1.0653

put all the values to get answer.

 

the position of both an electron and a helium atom is known within 1nm. further the momentum of the electron is known within 5*10-26 kgm/s. the minimum uncertainity in the measurement of the momentum of the helium atom is

 

Asked By: SHIVANI MALIK
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Joshi sir comment

according to Heisenberg principle product of uncertainity in position and momentum of a particle is greater than or equal to h/4π, since uncertanity in position of both the particle are same so same will be the momentum uncertainty minima.

the frequency of radiation emitted when the electron falls n=4 to n=1 in a hydrogen atom will be (given ionisation energy of H =2.18*I0-18 J/atom )

ans=3.08*1015

Asked By: SHIVANI MALIK
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Joshi sir comment

for n = 1                      E = 2.18*10-18

for n = 4                      E = 2.18*10-18/16

so hν = 15*2.18*10-18/16

so ν = 15*2.18*10-18/16*6.634*10-34

so ν = 3.08*1015

which of the following has highest energy?

1)S-S

2)O-O

3)Se-Se

4)Te-Te

Asked By: SHIVANI MALIK
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Joshi sir comment

O-O         498.36 kJ/mole

S-S         425.30 kJ/mole

Se-Se      332.6 kJ/mole

Te-Te      259.8 kJ/mole

which of the following has zero dipole moment?  and how?

1)1-butane

2)2-methyl, 1-propyl

3)cis 2-butane

4)trans 2-butane

Asked By: SHIVANI MALIK
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Joshi sir comment

i think it should be trans 2 butene 

1-what is the hybridisation of s and p in s8 and P4 respectively?

 

Asked By: SHWETA BHARDWAJ
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Joshi sir comment

sp3 both

How does Fridal craft reaxn can be given by ESTER                        

                              CH3COOCH2CH3

 

PLEASE HELP ME

PLEASE 

Asked By: AMAN
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Joshi sir comment

CH3CO--OC2H5

This is the form of ester. In the presence of anhydrous AlCl3, C6H6 will give reaction with ester 

JEE 2009 (MATRIX MATCH QUES.)

How  reaction takes place between                 

                                  CH3CH2CH2CH2NH2 and CHCl3/alco.KOH     giving foul smell.

PLEASE GUIDE ME.

PLEASE

Asked By: AMAN
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Joshi sir comment

This is well known Reimer Tiemann reaction

Product will be 

 CH3CH2CH2CH2NC

when 20 g of caco3 were put into 10 litre flask and heated to 800 degree cesius, 30% of caco3 remained unreacted at equilibrium. kp for decomposition of caco3 will be 1.231 ATM    HOWWWW............PLS SOLVE THIS ....PLS PLS..........

Asked By: PRATIBHA
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Joshi sir comment

CaCO3     ---------->   CaO   +   CO(g)

0.2 mole                   0            0

0.06                       0.14       0.14

so Kp= p                       only CO2 is gas so its pressure is considered 

now p = 0.14*0.0821*1073/10 

now solve

THE STRUCTURE OF HYDROGEN PEROXIDE IS NON-PLANER.HOW?

Asked By: SHIVANI MALIK
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Joshi sir comment

The structure of HYDROGEN PEROXIDE is like an open book. O-O bond is present in the joint and both H atom on the opposite side. Hybridisation will be sp3 for all bonds 

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